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Poly(tetrafluoroethylene) is synthesized by free radical polymerization of tetrafluoroethylene under high pressure and aqueous medium. It is a highly crystalline, linear and orientable polymer. Solvent and corrosion resistance is high but surface tension and friction coefficient are low. It has by far the lowest dielectric constant for all known polymeric materials. It is used in non-stick paints for painting kitchen items, hygienic bathroom and toilets.